Base metals are a group of metallic elements known for their wide industrial applications and essential properties. One defining characteristic of these metals is their susceptibility to oxidation and corrosion when exposed to air or moisture. This article aims to shed light on base metals, their common examples, and the reasons behind their reactivity.

Introduction to Base Metals

Base metals, as opposed to precious metals like gold and silver, encompass a range of elemental metals that are abundant in nature. They are widely utilized in various industries due to their malleability, electrical conductivity, and affordability. However, their propensity to oxidize and corrode is a significant factor that requires careful consideration in applications.

Common Examples of Base Metals

  1. Copper: This reddish-brown metal is well-known for its excellent electrical conductivity and heat resistance. It finds extensive use in electrical wiring, plumbing systems, and architectural applications. Copper gradually forms a greenish patina on its surface when exposed to air and moisture, known as copper oxide.
  2. Nickel: Often alloyed with other metals, nickel provides exceptional corrosion resistance. It is widely used in stainless steel production, electronics, and aerospace applications. Nickel’s ability to resist oxidation makes it valuable for maintaining structural integrity in various environments.
  3. Lead: Although its use has declined due to environmental concerns, lead was once prevalent in pipes, batteries, and ammunition. However, exposure to air and moisture leads to the formation of lead oxide and eventually corrosion, which poses health and environmental hazards.
  4. Zinc: This bluish-white metal is a vital component of galvanized steel, used in construction, automotive parts, and household appliances. Zinc acts as a sacrificial anode, protecting the underlying steel from corrosion by oxidizing itself.

Oxidation and Corrosion Mechanisms

The susceptibility of base metals to oxidation and corrosion can be attributed to their relative positions in the electromotive series. When exposed to oxygen or moisture, these metals undergo chemical reactions that result in the formation of metal oxides or other compounds.

Oxidation involves the loss of electrons by the metal atoms, leading to the creation of metal oxide compounds on the metal surface. Corrosion, on the other hand, is a broader term that encompasses the deterioration of metal due to chemical or electrochemical reactions with the surrounding environment.

Preventing Oxidation and Corrosion

While base metals are prone to oxidation and corrosion, various techniques can be employed to mitigate their impact:

  1. Coatings and Plating: Applying protective coatings or plating, such as zinc galvanization or nickel plating, forms a barrier between the metal and the environment, preventing direct exposure and reducing oxidation and corrosion.
  2. Alloying: Creating metal alloys by combining base metals with other elements can enhance their corrosion resistance and overall performance in specific applications.
  3. Environmental Control: Limiting exposure to moisture, humidity, and aggressive chemicals can significantly slow down the oxidation and corrosion processes.
  4. Cathodic Protection: In some cases, sacrificial anodes or impressed current systems are used to protect base metals by sacrificing a more reactive metal to corrosion.

Conclusion

Base metals are crucial components of modern industries, providing essential properties at a lower cost. However, their vulnerability to oxidation and corrosion necessitates careful material selection and protective measures during application. By understanding the behavior of base metals and implementing appropriate safeguards, industries can leverage their advantages while minimizing the impact of oxidation and corrosion.